Nitrate and halide ions coexist in particles generated in marine regions, around alkaline dry lakes, and in the Arctic snowpack. Although the photochemistry of nitrate ions in bulk aqueous solution is well known, there is recent evidence that it may be more efficient at liquid—gas interfaces, and that the presence of other ions in solution may enhance interfacial reactivity. This study examines the nm photolysis of thin aqueous films of ternary halide—nitrate salt mixtures NaCl—NaBr—NaNO 3 deposited on the walls of a Teflon chamber at K.
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